We currently manufacture
monochromator crystals from quartz, silicon, and germanium.
There are
many possible orientations for quartz and fewer for silicon and
germanium. Examples of quartz orientations are (2023),
(1011), and (1010). Silicon and germanium
orientations include (220), (111), and (400). A fairly complete
listing of useful orientations for these three crystals is given
at the end of this note along with 2d spacings.
All
monochromators that we manufacture are done on a custom basis.
If you can give us an
orientation and dimensions for a flat crystal, we can go from
there in terms of offering a quotation. Please, also include
the quantity that you need. Crystal surfaces can be either
ground or polished, depending on your specific requirements.
Our polished surfaces of quartz produce Bragg angles with about
10 arcseconds of angular spread for quartz and about 20
arcseconds for either silicon or germanium when used with Cu
K-alpha radiation. Unless specified, we assume the
crystals will be polished
Crystal:QuartzSiliconGermanium
Orientation
(Miller Indices):
hkl
Crystal Geometry:
FlatToroidal
Dimensions::
Please, provide drawing or sketch, if possible.
Here are
general guidelines for choosing dimensions, based on
our present capabilities.
If toroidally
bent, radii should be in the range of 0.2 meters to
1.0 meters. If spherically bent, then the radius
can be up to 2.0 meters and longer.
Finished
crystal size is dependent on 1) the availability of
large, high quality raw crystals, and 2) the ability
of the crystal to bend to the required radius or
radii. A convenient strip for bending is 50 mm x 15
mm. Such rectangular crystal strips, which are in
the ration of 1:0.3, can be manufactured with a
maximum size of ~100 mm x 30 mm. For ease of
manufacture, the maximum circular crystal is about
50 mm. These circular crystals can be used when the
backing radius is in the several meter range.
The above
dimensional comments are meant as rough guidelines
only. We always are pleased to consider the
specifics of your application, even though they may
not be an exact match to these guidelines.
Quantity:
In case you are interested in curved crystals, then
you may find our datasheet on toroidally figured
crystals informative.
Applications for these
toroidally curved X-ray crystals include use in
analytical chemistry micro-probes (or ESCA), in
monochromatic imaging of hot plasmas, and in
ultra-fast probing of structural changes in
materials.
Large-area elements can be assembled from single
crystals if the bend radius is large, or from a
mosaic of smaller crystals.
Selected X-Ray Data
Selected Data for
Inter-Planar Spacing of Quartz, Silicon, and
Germanium
Inter-planar Spacing for
High Quality Crystals
Crystal
Miller Indices
2d ( Å )
α-Quartz SiO2
(5052)
1.624
(2243)
2.024
(3140)
2.3604
(2240)
2.451
(2023)
2.749
(2131)
3.082
(1122)
3.636
(2020)
4.246
(1012)
4.564
(1120)
4.912
(1011)
6.687
(1010)
8.5096
Ge Germanium
(400)
2.828
(220)
4.00
(111)
6.532
Si Silicon
(220)
3.8403117
(111)
6.2712
Data for the table
below was extracted from Table 4-1 of the “X-Ray
Data Booklet”, second edition, January 2001,
Lawrence Berkeley National Laboratory, University of
California, Berkeley, CA 94720. Note, we have added
the Ge(400) entry to this table.